論文2014

原著論文

  1. Koji Kawai, Hayato Kawakami, Takashi Narushima, and Tetsu Yonezawa* “Selective and reactive hydration of nitriles to amides in water using silver nanoparticles stabilized by organic ligands” Journal of Nanoparticle Research17, 60 (9 pages) (2015).
    DOI: 10.1007/s11051-014-2816-1 (First Published Online 30 January 2015)
    Abstract: Water-dispersible silver nanoparticles stabilized by silver–carbon covalent bonds were prepared. They exhibited high catalytic activities for the selective hydration of nitriles to amides in water. The activation of a nitrile group by the functional groups of the substrates and the hydrophobic layer on the nanoparticles influenced the catalyzed reaction were confirmed. Alkyl nitriles could also be selectively hydrated.
  2. Masashi Chiba, Mai Nguyen Thanh, Yasuchika Hasegawa, Yasushi Obora, Hideya Kawasaki, and Tetsu Yonezawa* “Synthesis of Binary Solid Solution Cu-Pd Nanoparticles by DMF Reduction for Enhanced Photoluminescent Properties” Journal of Materials Chemistry C3(3), 514-520 (2015).
    DOI:10.1039/C4TC02129K(First Published Online 07 November 2014)

    GA Abstract: We report the use of a DMF reduction method for straightforward synthesis of binary solid solution Cu–Pd nanoparticles (NPs) over the entire range of composition. The resulting NPs were uniform in size (less than 2.5 nm), tunable in composition, and exhibited photoluminescence properties that were nonlinear in composition. These binary solid solution NPs showed enhanced photoluminescence intensity and quantum yield compared to those of the single-metal NPs and their mixtures. The highest quantum yield of 3.10% for Cu–Pd alloy NPs synthesized using equimolar feeding ratio versus 2.75% for Cu and 0.71% for Pd NPs was obtained. These enhancements make the alloy NPs promising materials for optical applications.

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  3. Chaorui Xue, Takashi Narushima, Yohei Ishida, Tomoharu Tokunaga, and Tetsu Yonezawa* “Double-Wall TiO2 Nanotube Arrays: Enhanced Photocatalytic Activity and In situ TEM Observations at High Temperature” ACS Applied Materials & Interfaces6(22), 19924-19932 (2014). (17 Nov. 2014)
    DOI:10.1021/am505333v
  4. Kazutaka Hirakawa, Yumi Yamaji, Tetsu Yonezawa, and Naoki Toshima “Reduction of carbon dioxide using a visible-light-induced electron transfer system with colloidal metal nanoparticle catalysts: Evidence for puroduction of methane” Current Topics in Catalysis11, 55-63 (2014) Abstract
  5. Shigeaki Abe, Atsushi Hyono, Koji Kawai, Koichi Nakamura, Yasutaka Yawaka, Yasuhiro Yoshida, and Tetsu Yonezawa “Simple and Rapid Conductive Preparation of Wet Biological Samples for SEM Observation: Use of an Asymmetrical Choline-like Room Temperature Ionic Liquids as a Visualizaing Agent” Nano Biomedicine6(1), 41-46 (2014).
  6. Gang Qin, Akira Watanabe, Hiroki Tsukamoto, and Tetsu Yonezawa “Copper Film Prepared from Copper Fine Particle Paste by Laser Sintering at Room Temperature: Influences of Sintering Atmosphere on the Morphology and Resistivity” Japanese Journal of Applied Physics53(9), 096501 (2014).
    DOI:10.7567/JJAP.53.096501 (6 August 2014)
  7. Chaorui Xue, Takashi Narushima, Yohei Ishida, Tomonaru Tokunaga, and Tetsu Yonezawa “In situ TEM Observation of Double-Wall TiO2 Nanotube Arrays at High Temperature” Chemistry Letters43(9), 1514-1516. PDF
    DOI:10.1246/cl.140486 (5 September 2014)
  8. Shigeaki Abe,* Atsushi Hyono, and Tetsu Yonezawa “Influence of surface properties for SEM observation of carbon nanotubes pretreated with Room Temperature Ionic Liquid” Journal of Solution Chemistry43(9-10), 1645-1654 (2014)
    DOI: 10.1007/s10953-014-0230-z (18 October 2014)
  9. Masanori Hashimoto, Hirokazu Toshima, Tetsu Yonezawa, Koji Kawai, Takashi Narushima, Masayuki Kaga, Kazuhiko Endo “Responses of RAW264.7 macrophages to water-dispersible gold and silver nanoparticles stabilized by metal–carbon σ-bonds” Journal of Biomedical Materials Research A102(6), 1838-1849 (2014).
    DOI: 10.1002/jbm.a.34854 (online 2 Jul 2013)
  10. Atsushi Hyono, Tetsu Yonezawa, Koji Kawai, Shigeaki Abe, Mitsuhiro Fujihara, Hiroshi Azuma, and Shinobu Wakamoto “SEM observation of the live morphology of human red blood cells under high vacuum conditions using a novel RTIL” Surface Interface Analysis46(6), 425-428 (2014).
    DOI: 10.1002/sia.5471 (online 1 Apr 2014)
  11. Atsushi Hasegawa, Masamitsu Yoshiki, Tsuguhito Nakano, Kohji Abe, Susumu Sato, and Tetsu Yonezawa “Alignment of Needle TiO2 Nanoparticles in Water” International Journal of Theoretical and Applied Nanotechnology2(1), 18-23 (2014).
    DOI: 10.11159/ijtan.2014.003 (31 Mar 2014)
  12. Tetsu Yonezawa,* Yoshiki Uchida, and Yuki Abe “Formation Process of Metallic Copper Fine Particles from Cupric Oxide Microparticle at Room Temperature” Journal of Nanoscience and Nanotechnology14(7), 5402-5407 (2014)
    DOI: 10.1166/jnn.2014.7919 (1 Jul 2014)
  13. Shigeaki Abe,* Atsushi Hyono, Koji Kawai, and Tetsu Yonezawa “Visualizing Preparation Using Asymmetrical Choline-Like Ionic Liquids for Scanning Electron Microscope Observation of Non-Conductive Biological Samples” Journal of Nanoscience and Nanotechnology14(3), 2620-2623 (2014)
    DOI: 10.1166/jnn.2014.8629 (1 Mar 2014)
  14. Masanori Hashimoto, Hirokazu Toshima, Tetsu Yonezawa, Koji Kawai, Masahiro Iijima, Kazuhiko Endo “Evaluation of Silver Nanoparticle Toxicity to RAW264.7 Cells in a Three-Dimensional Cell Culture” Journal of Biomaterials and Tissue Engineering4(1), 51-58 (2014)
    DOI: 10.1166/jbt.2014.1141 (1 Jan 2014)
  15. 成島 隆・Ren Lu・米澤 徹 「有機保護分子をもたないウニ型Ni微粒子の湿式合成とその場TEMによる高温挙動観察」 日本金属学会誌、78(2), 98-102 (2014) “Wet Preparation of Organic Stabilizer Free Urchin Structured Nickel Fine Particles and Their in-situ TEM Observation at High Temperature” Journal of the Japan Institute of Metals and Materials78(2), 98-102 (2014).
    DOI:10.2320/jinstmet.J2013073 (1 Feb 2014) Takashi Narushima, Ren Lu, and Tetsu Yonezawa “Wet Preparation of Organic-Stabilizer-Free Urchin Structured Nickel Fine Particles and Their In situ TEM Observation at High Tempeartures” Materials Transactions55(9), 1474-1478. (Aug 2014)
    DOI:10.2320/matertrans.M2014176
    (日本金属学会は、和文誌と同様の内容を英文誌にも掲載していただけることになっています)
  16. Tomomi Takeshima, Ling Sun, Yanqing Wang, Yoshihisa Yamada, Norio Nishi, Tetsu Yonezawa, and Bunshi Fugetsu “Salmon milt DNA as a template for the mass production of Ag nanoparticles” Polymer Journal46(1), 36-41 (2014).
    DOI:10.1038/pj.2013.58 (on line 25 June 2013)

総説・解説

  1. Tetsu Yonezawa “Metal Nanoparticles” in “Encylopedia of Polymeric Nanomaterials”, Springer Press, in press. DOI: 10.1007/978-3-642-36199-9_125-1
  2. 成島 隆・米澤 徹 「金属ナノ粒子の形状変化の高温その場TEM観察」 顕微鏡、49(2), 88-92. (査読有)
  3. 「新しいナノ粒子とそのグリーン合成法 ~目的に応じた材料創製をめざして~」 北海道大学教授 米澤 徹氏に聞く NanotechJapan Bulletin, 7(1). Published on 28 Feb 2014
    https://nanonet.go.jp/magazine/?plugin=pgid&id=1098
  4. 本野真梧・米澤 徹 「電子部品・触媒に用いることのできるナノ粒子の新しいグリーン合成法」 化学工学、78(3), 196-198 (2014)
  5. 米澤 徹 「安定な金属ナノ粒子のコロイド化学・分散とその調製」 塗装工学、49(2), 42-50 (2014)
  6. 米澤 徹 「金をベースとするナノ粒子を俯瞰する」 オレオサイエンス, 14(1), 11-15 (2014). “Overlook of Gold Nanoparticles and Other Metal Nanoparticles Containing Gold”